3-Benzyl-5-(2-hydroxyethyl)-4-methyl-1,3-thiazolium chlorochromate (BCC) as oxidizing agent | Abstract

Der Pharma Chemica
Journal for Medicinal Chemistry, Pharmaceutical Chemistry, Pharmaceutical Sciences and Computational Chemistry

ISSN: 0975-413X
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3-Benzyl-5-(2-hydroxyethyl)-4-methyl-1,3-thiazolium chlorochromate (BCC) as oxidizing agent

Author(s): Ponnapali Veerabhadra Swamy, Srinuvasu Nakkaa, Balram B, Ram B, Subramanyam D, Saidu Reddy Sakam, Taara B

Selected alcohols and oximes undergo oxidative cleavage to corresponding carbonyls by employing BCC, in chloroform as solvent under reflux conditions. It is found that this reagent also shows similar selectivity and mechanism for the oxidation of alcohols and oximes as PCC (pyridinium chlorochromate), MCC (1-methyl imidazolium chlorochromate), ICC (imidozolium chlorochromate) and QFC (quinolium fluorochromate).


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