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Acid catalyzed and thermal rearrangements of 1-(?Ž?±-branched alkoxy) naphthalenes | Abstract

Der Pharma Chemica
Journal for Medicinal Chemistry, Pharmaceutical Chemistry, Pharmaceutical Sciences and Computational Chemistry

ISSN: 0975-413X
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Abstract

Acid catalyzed and thermal rearrangements of 1-(?Ž?±-branched alkoxy) naphthalenes

Author(s): Sreenivasula Reddy Bandatmakuru, Srinivasulu Reddy Amasa, Veera Reddy Arava*, and Subha MCS

Acid catalyzed and thermal rearrangements of 1-(α-branched alkoxy) naphthalenes are studied. The intermediate carbonium ion is established by crossover experiments under acidic rearrangement conditions. The disubstituted product of the acidic rearrangement is corroborated by single crystal structure analysis. Thermal rearrangements are studied in detail.


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