GET THE APP

Oxidative cleavage of lysine by nicotinium dichromate in aqueous medium in presence of perchloric acid | Abstract

Der Pharma Chemica
Journal for Medicinal Chemistry, Pharmaceutical Chemistry, Pharmaceutical Sciences and Computational Chemistry

ISSN: 0975-413X
All submissions of the EM system will be redirected to Online Manuscript Submission System. Authors are requested to submit articles directly to Online Manuscript Submission Systemof respective journal.

Abstract

Oxidative cleavage of lysine by nicotinium dichromate in aqueous medium in presence of perchloric acid

Author(s): Vivekanandan K and Lakshmi Narayanan R

The oxidation of an essential amino acid like lysine by nicotinium dichromate in aqueous medium in the presence of perchloric acid was studied. The reaction was first order with respect to oxidant, fractional order with respect to substrate and second order with respect to perchloric acid. The increase in ionic strength had negligible effect on the rate. Amino acid was converted to the corresponding carbonyl compound. No polymerisation was observed with acrylonitrile. The addition of Mn2+ ion had a noticeable catalytic effect on the rate. The rates were determined at four different temperatures and the thermodynamic parameters were evaluated.


PDF

Select your language of interest to view the total content in your interested language

30+ Million Readerbase
SCImago Journal & Country Rank
Google Scholar citation report
Citations : 23677

Der Pharma Chemica received 23677 citations as per Google Scholar report

Der Pharma Chemica peer review process verified at publons
Der Pharma Chemica- Journals on pharmaceutical chemistry