VTPS is one of the major sources for electricity to Andhra Pradesh state. It was located in Kondapalli village on Vijayawada-Hyderabad National Highway. Approximately 13 villages are there around of VTPS. In VTPS electricity is producing by rotating of turbines with steam of Krishna river water. Present study is carried out to determine the physicochemical characteristics of ground water of Kondapalli nearby VTPS-Vijayawada. There is no change in PH from location to location but there is difference between three seasons. Heavy metals are found in few places. Hardness, D.O, COD, Chloride, Fluoride and remaining parameters are analyzed and compared with IS 10500:2012 drinking water specifications.