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Silver(I) ion selective transport through a bulk liquid membrane containing 5,12-di(phenoxymethyl)-1,4-dioxa-,10-ithiacyclododecane- 2,3-dione as carrier | Abstract

Der Pharma Chemica
Journal for Medicinal Chemistry, Pharmaceutical Chemistry, Pharmaceutical Sciences and Computational Chemistry

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Abstract

Silver(I) ion selective transport through a bulk liquid membrane containing 5,12-di(phenoxymethyl)-1,4-dioxa-,10-ithiacyclododecane- 2,3-dione as carrier

Author(s): Malihe Sadat Hosseiny, Gholam Hossein Rounaghi and Mahmud Chamsaz

5,12-Di(phenoxymethyl)-1,4-dioxa-7,10-dithiacyclododecane-2,3-dione is an excellent synthetic carrier for highly efficient and selective transport of Ag(I) ions through a liquid membrane. In the presence of thiosulfate as stripping agent in the receiving phase and at the optimum pH of 4, about 80% of silver was transported over a period of 5 h. The carrier can selectively and efficiently transport Ag(I) ion from aqueous solutions containing other cations such as Co2+, Cu2+, Zn2 +, Pb2+, Cr3+, Cd2+.


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