Der Pharma Chemica
Journal for Medicinal Chemistry, Pharmaceutical Chemistry, Pharmaceutical Sciences and Computational Chemistry
ISSN: 0975-413X
Abstract
Synthesis and characterization tris N-2,4-dinitrophenyl N/-3-nitrobenzylidenehydrazine palladium chloride and tris N-2,4- dinitrophenyl N/-3-phenyl alilidine hydrazine
Author(s): Mohamad Mehdi Akbarzade* and Ali NaderiThe reaction between two acetohydrazide ligands that are, N-2,4dinitrophenyl N/-3-nitrobenzylidenehydrazine and Tris N-2,4dinitrophenyl N/-3-phenyl alilidinehydrazine with PdCl2 produced two new ionic palladium complexes. One of them is TNBH which is easily synthesized in a nearly quantitative yield using a direct reaction between PdCl2 and N-2,4dinitrophenyl N/-3-nitrobenzylidenehydrazine. Another is TDPH which has been synthesized by the reaction of Tris N-2,4dinitrophenyl N/-3-phenyl alilidinehydrazine with PdCl2. These compounds are characterized by spectroscopic techniques. The electronic and vibrational spectra of TDPH and TNBH have been measured and studied.
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