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Synthesis and Structural Investigation on Symmetrically Substituted Metal(II)- 3-prop-phenyl-2-en-1-Imine Phthalocyanine. | Abstract

Der Pharma Chemica
Journal for Medicinal Chemistry, Pharmaceutical Chemistry, Pharmaceutical Sciences and Computational Chemistry

ISSN: 0975-413X

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Abstract

Synthesis and Structural Investigation on Symmetrically Substituted Metal(II)- 3-prop-phenyl-2-en-1-Imine Phthalocyanine.

Author(s): Fasiulla, Yashoda MP, Venugopala Reddy KR and Anitha

Present paper discuss the synthesis and characterization of metal (II) octa-(2e)-3-prop-phenyl-2-en-1-imine phthalocyanines (M-PropPhImPcO) (M = Cu, Co, Ni, Zn) by an efficient, simple, and novel method. Octaamino metal (II) phthalocyanines were synthesized by the reduction of the corresponding nitro phthalocyanines. The dark green octa-1-(3-nitrophenyl) methaniminephthalocyanine derivatives were characterized by elemental analysis, magnetic susceptibility, electronic, IR and powder X-ray diffraction studies to check the purity, structural integrity and crystalline properties of the complexes. Magnetic susceptibility studies on Co (II) and Cu (II) octa-(2e)-3-propphenyl- 2-en-1-iminephthalocyanine complexes exhibit a variation of the magnetic moments as a function of field strength indicating the presence of inter molecular co-operative effect.


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