Der Pharma Chemica
Journal for Medicinal Chemistry, Pharmaceutical Chemistry, Pharmaceutical Sciences and Computational Chemistry
ISSN: 0975-413X
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Abstract
Trichloroisocyanuric acid: A cost effective commercial and mild system for the oxidation of primary alcohols to aldehydes
Author(s): Sahadev Reddy M, M. S. N. Reddy, Rajan S. T.a, Bapaiah B and Chakravarthy I. E.An improved and efficient synthetic process developed for an oxidation of primary alcohols to related aldehydes with commercially cheaper trichloroisocyanuric acid in presence of catalyst TEMPO (2, 2, 6, 6-tetra methyl-1- piperidinyloxy Free radical). This synthetic approach efficiently provides highly pure aldehydes without formation of the acid impurity. In the present process overall yields are around 90-95%.
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