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Viscometric and thermodynamic study of substituted-N,Nâ??bis(salicyliden) arylmethanediamine in a binary system of 70% DMF-Water | Abstract

Der Pharma Chemica
Journal for Medicinal Chemistry, Pharmaceutical Chemistry, Pharmaceutical Sciences and Computational Chemistry

ISSN: 0975-413X
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Abstract

Viscometric and thermodynamic study of substituted-N,Nâ??bis(salicyliden) arylmethanediamine in a binary system of 70% DMF-Water

Author(s): A. S. Chandami, D. S. Hedaoo and M. P. Wadekar

The viscometric and thermodynamic measurements of substituted- N,N’bis(salicyliden)-arylmethanediamines in a binary mixture were performed. Density and viscosity measurements were carried out in 70% DMF-Water mixture at different temperatures. The viscometric measurements were done with the help of Ostwald’s viscometer. The data so obtained were analyzed by using Jones-Dole equation. This study helps to predict the molecular interaction in solution mixture. The present study deals with the determination of the thermodynamic parameters such as Gibbs free energy change (ΔG), enthalpy change (ΔH) and entropy change (ΔS).


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