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Electrophilic Effects of Copper ions on kinetics of dissociation of Tris (1,10- Phenanthroline) iron (II) in Sodium dodecyl sulphate micellar medium | Abstract

Der Pharma Chemica
Journal for Medicinal Chemistry, Pharmaceutical Chemistry, Pharmaceutical Sciences and Computational Chemistry

ISSN: 0975-413X

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Abstract

Electrophilic Effects of Copper ions on kinetics of dissociation of Tris (1,10- Phenanthroline) iron (II) in Sodium dodecyl sulphate micellar medium

Author(s): V TejeswaraRao, K Balaji, Satya guru TVSPV and S Raju*

Many metal ions have been found to exert electrophilic effects on the dissociation of complexes and it has been proposed that a ternary intermediate is formed involving the complex and metal ion through the severing of one of the metal ligand bonds. To investigate this aspect, the dissociation of Fe (phen)32+ and effects of metal ion like Cu2+ in the presence of SDS micelles providing anionic micellar surface. These results confirm that the formation of such a ternary intermediate and marked micellar catalysis of the reaction.


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