Research Article
Electrophilic Effects of Copper ions on kinetics of dissociation of Tris (1,10- Phenanthroline) iron (II) in Sodium dodecyl sulphate micellar medium
Author(s): V TejeswaraRao, K Balaji, Satya guru TVSPV and S Raju*
Many metal ions have been found to exert electrophilic effects on the dissociation of complexes and it has been proposed that a ternary intermediate is formed involving the complex and metal ion through the severing of one of the metal ligand bonds. To investigate this aspect, the dissociation of Fe (phen)32+ and effects of metal ion like Cu2+ in the presence of SDS micelles providing anionic micellar surface. These results confirm that the formation of such a ternary intermediate and marked micellar catalysis of the reaction... Read More»