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Intermolecular Free Length And Molar Volume Of Binary Liquid Mixtures Of Ethyl Acetate With 1-alkanol At 303.15K | Abstract

Der Pharma Chemica
Journal for Medicinal Chemistry, Pharmaceutical Chemistry, Pharmaceutical Sciences and Computational Chemistry

ISSN: 0975-413X

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Abstract

Intermolecular Free Length And Molar Volume Of Binary Liquid Mixtures Of Ethyl Acetate With 1-alkanol At 303.15K

Author(s): Dhirendra Kumar Sharma*, Seema Agarwal and Akil Khan

The ultrasonic velocity (u) and density (ρ) have been measured for ethyl acetate with 1-alkanols at 303.15K, over the entire range of composition. The thermodynamic parameter such as intermolecular free length (Lf), molar volume (Vm), isentropic compressibility (βs) and internal pressure (Pi) have been obtained for all mixtures from experimental data with a view to investigating the exact nature of the molecular interaction. The excess values of the said parameter have also been calculated. The deviation from ideality of these parameters is explained on the basis of molecular interactions between the constituent components of the mixture.


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